X-rays of the wrist are the usual way to diagnose a scaphoid fracture, but unless the scaphoid was moved out of place, x-rays taken in the week after the injury may not show the fracture and it may be considered a sprain.
If the area right above the scaphoid, in the hollow "snuffbox" where the thumb meets the wrist, is very tender, a scaphoid fracture is likely and a splint should be used to protect the bone. A couple weeks after the injury, a second x-ray will usually confirm whether or not the scaphoid was fractured by showing changes in the bone at the sight of the fracture.
Sometimes it may be hard to wear a splint for two weeks, or the second x-ray might still fail to show the fracture even though the hand surgeon feels it is likely. While they cost more than an x-ray, an MRI, CT, or bone scan can often show if the scaphoid was fractured.